Purchase stock - expense vouchers?

[Lloyd]

A simple question from a beginner.

I'm trying to move my wifes small business over to gnucash from the
spreadsheet she currently uses.  Basically, all manufacturing material is
purchased by her or myself, and then we reimburse ourselves from petty cash. 
Would I be correct to do this through expense vouchers?

Supplementary questions  - what is the Billing Id used for on an expense
voucher?

Thanks

Lloyd

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